| Facts on Fish Keeping WHAT IS CARBONATE HARDNESS
A Carbonate Hardness test is a test of the carbonate and bicarbonate extent contained in a
sample of water. It affects all aquaria, both salt and fresh. It is called many names,
according to the jargon of an industry or country of origin of the test kit.
CARBONATE HARDNESS = ALKALINITY=kH(German) =ACID BINDING CAPACITY.
The units used to measure Carbonate Hardness depends on the name of the Test Kit. For
instance, if the Test Kit is called Alkalinity, the test would be measured in
milliequivalents. kH test kits usually use dH (German) and Carbonate Hardness is usually
measured in ppm (parts per million).
(10//ppm = 1 meq/1 = 2.8dH (German).
STABILITY OFpH
The Carbonate Hardness of water is an important measurement, both in freshwater and marine
because the level of Carbonate Hardness is the basis for the value of the pH in a given
sample of water. A strong Carbonate Hardness reserve in water can mean a very stable pH
and the bonus of an alternative supply of carbon dioxide for plants and algae if supply
runs short in an aquarium. This applies equally for marine or freshwater aquaria.
Freshwater aquariums are recommended by German literature to have between 85ppm to 170ppm
Carbonate hardness, while, in marine aquariums, the minimum is 125ppm with a recommended
maximum around 250ppm. Sea water has a natural Carbonate Hardness of 125ppm.
DEPLETION OF THE CARBONATE HARDNESS RESERVE
Acids which form as a result of the breakdown of waste products by bacteria (via
biological filtration) is the most common way the carbonate hardness reserve is depleted.
As a carbonate hardness reserve is depleted, the pH drops. In aquariums with no carbonate
hardness the pH is very unstable. An example might be:- the pH may be adjusted to 7.00 in
a freshwater aquarium with a reasonable stock load, but because the carbonate hardness is
low (less than 20ppm) the pH falls rapidly overnight and by the next day has again turned
acid.
CARBONATE HARDNESS AND PLANTS.
A low Carbonate Hardness usually has a negative effect on the growth of plants. While a
strong Carbonate hardness (around 100ppm) has a positive effect. This is evident in the
strong plant growth in streams that flow from limestone terrain. This natural phenomenon
may be recreated in aquaria by strong water movement and manipulation of the carbonate
hardness level.
CARBONATE HARDNESS AND INVERTEBRATES.
While marine fish seem to be little affected by a temporary low carbonate hardness and the
resulting low pH, most invertebrates can be seriously affected, some irreparably. Live
corals appear to do better in aquaria when carbonate hardness levels are above the natural
level of 125ppm. Carbonate hardness at levels above 125ppm seem to aid the Zooanthellie
algae living symbiotically with the coral and also may aid hard corals in extracting
calcium from sea water.
RAISING CARBONATE HARDNESS IN MARINE SYSTEMS.
Use Aquasonic kH-UP Carbonate Hardness generator tablets. 1 tablet per 120L raises the
carbonate hardness by approx.20ppm. No adjustments to pH are necessary. The tablets, which
take up to 24 hours to dissolve, are best used by placing them in the filter chamber.
Monitor carbonate hardness levels with an Aquasonic Carbonate Hardness Test Kit.
STABILISING pH IN FRESHWATER AQUARIUMS
To stabilise the pH in freshwater aquariums, the carbonate hardness needs to be raised to
levels above 60ppm with recommended levels around 90ppm. This is achieved easily with
Aquasonic kH-UP Carbonate Hardness generator tablets. 1 tablet raises the carbonate
hardness of 120L of water by approx. 20ppm. The tablets dissolve within 24 hours. Monitor
the carbonate hardness, with an Aquasonic Carbonate Hardness test kit, daily until the
desired level is obtained. As the carbonate hardness level rises, so too will the pH.
pH ADJUSTMENT
METHOD (A)
The pH may be adjusted down to a desired level with Aquasonic "pH-LOWER".
Dose rates are 5ml per 20L. Wait for 12 hours to allow complete mixing then re-test the pH
to determine if re-dosing is necessary. It is recommended that the pH be set at around 7.0
to 7.2. This process of raising the carbonate hardness and then setting the pH, will form
a buffer which will hold the pH stable. This stability will last until the carbonate
hardness reserve is depleted, of course regular additions of "kH-UP" tablets
will replenish the carbonate hardness reserve.
METHOD (B)
The pH may be controlled with carbon dioxide infusion. the strength of the reserve and the
quantity of carbon dioxide infused will determine the pH. For pH to read without carbon
dioxide interference, carbon dioxide has to be in equilibrium with the atmosphere.
Carbonate hardness is the basis of the pH, but this pH value can be over-ridden by
increasing the carbon dioxide levels causing a lower pH.
Published by AQUASONIC
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